Application of Radiation-Grafted Polymer Electrolyte Membranes to the Bunsen Reaction

نویسندگان

  • Nobuyuki Tanaka
  • Masaharu Asano
  • Kaoru Onuki
  • Yasunari Maekawa
چکیده

Bunsen reaction was performed electrochemically using cation exchange membranes prepared by a radiation-induced grafting method for application to the iodine-sulfur thermochemical water-splitting cycle. The reaction experiments using sulfuric acid dissolving sulfur dioxide as the anolyte and hydriodic acid dissolving iodine as the catholyte verified the progress of the aimed reaction. Compared with Nafion 117, the radiation-grafted membranes showed lower electric resistance in the reaction condition, whereas they were less selective to proton permeation.

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تاریخ انتشار 2008